WebThe Escherichia coli genotoxin colibactin is synthesized by a multi-protein machinery composed of non-ribosomal peptide synthetase (NRPS)/polyketide synthase (PKS) enzymes. In order to decipher the function of a PKS-NRPS hybrid enzyme, Bonhomme et al. determined the crystal structure of the ClbK-PKS module and performed SAXS … WebBoth compounds 3 and 4 are monomeric species in the solid state, and the molecular geometries are governed by a stereo-active lone pair at the metal centers. Two new main group element carboranylamidinates were synthesized using a bottom-up approach starting from o-carborane, ortho-C2B10H12 (1, = 1,2-dicarba-closo-dodecaborane).
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